2-Chloro-N-(3-methylphenyl)benzamide
نویسندگان
چکیده
In the structure of the title compound, C(14)H(12)ClNO, the ortho-Cl atom in the benzoyl ring is positioned syn to the C=O bond, while the meta-methyl group in the aniline ring is positioned anti to the N-H bond. The amide group forms dihedral angles of 60.1 (1) and 22.0 (1)°, respectively, with the benzoyl and aniline rings, while the angle between these rings is 38.7 (1)°. The crystal structure is stabilized by N-H⋯O hydrogen bonds, which give rise to infinite chains running along the c axis.
منابع مشابه
N-(4-Methylphenyl)benzamide
The structure of the title compound, C(14)H(13)NO, resembles those of N-(2-chloro-phen-yl)benzamide, 2-chloro-N-phenyl-benzamide, N-(2,3-dichloro-phen-yl)benzamide, N-(3,4-dichloro-phen-yl)benzamide and 2-chloro-N-(2-chloro-phen-yl)benzamide with similar bond parameters. The benzene and methylphenyl rings have a dihedral angle of 63.41 (5)°, while the amide group makes a dihedral angle of 20.5 ...
متن کامل2-Chloro-N-(2-methylphenyl)benzamide
In the title compound, C(14)H(12)ClNO, the two aromatic rings are almost coplanar, making a dihedral angle of 4.08 (18)°. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into infinite chains running along the a axis.
متن کامل4-Chloro-2-hydroxy-N-(4-methylphenyl)benzamide
In the title compound, C(14)H(12)ClNO(2), the dihedral angle between the aromatic rings is 14.87 (11)° and an intra-molecular N-H⋯O hydrogen bond generates an S(6) ring. In the crystal, mol-ecules are linked by O-H⋯O hydrogen bonds, generating C(6) chains propagating along the c-axis direction.
متن کامل4-Chloro-N-(3-methylphenyl)benzamide
In the title compound, C(14)H(12)ClNO, the meta-methyl substituent in the aniline ring is positioned anti to the N-H bond. The dihedral angle between the rings is 12.4 (1)°. The crystal structure is stabilized by inter-molecular N-H⋯O hydrogen bonds, which link the mol-ecules into C(4) chains running along the c-axis direction.
متن کامل2-Chloro-N-(4-methylphenyl)benzamide
In the title compound, C(14)H(12)ClNO, the ortho-Cl atom in the benzoyl ring is positioned syn to the C=O bond. The benzoyl and aniline benzene rings are tilted relative to each other by 82.8 (1)°. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into infinite chains running along the c-axis direction.
متن کامل2-Chloro-N-(3,5-dichlorophenyl)benzamide
The amide group in the structure of the title compound (N35DCP2CBA), C(13)H(8)Cl(3)NO, is trans-planar, similar to that observed in N-(3-chloro-phen-yl)benzamide, N-(3,5-dichloro-phen-yl)benzamide, 2-chloro-N-phenyl-benzamide and other benzanilides. The C=O bond in N35DCP2CBA is anti to the ortho-chloro substituent in the benzoyl ring. The amide group makes dihedral angles of 63.1 (12) and 31.1...
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